Synopsis: A Bumpy Ride for Atoms

Aging in metallic glasses occurs via intermittent rearrangements of the atoms and is not a steady, continuous process as previously thought.
Synopsis figure
Z. Evenson et al. Phys. Rev. Lett. (2015)

Metallic glasses—alloys with an amorphous glasslike structure—are popular technological materials because of their strength and resistance to fracture. However, these properties can decay over time, making the glass more brittle and prone to cracking. How this “aging” occurs, though, is unclear: Macroscopic measurements suggest a slow and steady rearrangement of the alloy’s atoms, but atomic-scale probes indicate a more complex and heterogeneous process. Providing support for this second picture, Zach Evenson at the Technical University Munich, Germany, and colleagues show that aging of a metallic glass occurs via localized and intermittent rearrangements of atoms. Understanding how atoms behave in metallic glasses as they age could allow more robust versions of these materials to be designed.

Evenson and co-workers cooled a palladium-based metallic glass from a liquid to a glassy state. Using x rays, they monitored the subsequent density fluctuations of the alloy as a function of time. These fluctuations are proportional to the frequency of the structural rearrangement of the atoms. They found that just after the glass had formed, it sat in a uniform state with density fluctuations that stayed constant with time. The alloy then entered an “aging” regime with slower density fluctuations. This slow down was not a continuous process; instead, the density fluctuations abruptly decreased to a fixed value, stayed there for a short period of time, and then abruptly dropped again—much like stop-and-go traffic on a congested freeway. Evenson and colleagues think these complicated dynamics indicate a system in which internal stresses, stored at the atomic level, relax in an intermittent and discontinuous manner.

This research is published in Physical Review Letters.

–Katherine Wright


Features

More Features »

Announcements

More Announcements »

Subject Areas

Materials Science

Previous Synopsis

Next Synopsis

Quantum Physics

Putting Quantum Systems to Work

Read More »

Related Articles

Synopsis: Universal Scaling Laws for 2D Schottky Diodes
Materials Science

Synopsis: Universal Scaling Laws for 2D Schottky Diodes

Long-sought simple scaling laws could pave the way for optimization of a vast array of 2D electronics. Read More »

Synopsis: Grain Properties in a Single Shot
Materials Science

Synopsis: Grain Properties in a Single Shot

The size and shape distributions of a material’s grains can be obtained from a 2D image and electron diffraction data.   Read More »

Synopsis: How Defects Alter Graphene Nanoribbons
Graphene

Synopsis: How Defects Alter Graphene Nanoribbons

Molecular defects can improve the mechanical flexibility of graphene nanoribbons without affecting their electrical properties, new experiments show. Read More »

More Articles