Synopsis

On-Demand Chemical Bond Formation

Physics 8, s68
A tailored laser pulse controls the formation of a molecular bond between two atoms.
Christiane Koch/Universität Kassel and Zohar Amitay/Technion-Israel Institute of Technology

The result of a chemical reaction is dictated by energy potentials and thermodynamics, but physicists have long hoped to steer reactions in new ways with coherent light from lasers. For the first time, researchers demonstrate the coherent control of the reaction by which two atoms form a molecule. The achievement—coupled with other photocatalyst tools—could potentially lead to a chemical assembly line, in which lasers slice and weld molecular pieces into a desired end product.

Coherent control of chemical reactions, which was first proposed thirty years ago, employs shaped laser pulses to place molecular reagents in states that promote a rare reaction process. Several groups have succeeded in controlling which bonds are cut in a target molecule (i.e., selective photodissociation). However, the coherent control of bond formation has proven more elusive.

A collaboration between experimentalists at Technion-Israel Institute of Technology in Haifa, Israel, and theorists at the University of Kassel in Germany has now controlled the photoassociation of a simple molecule. The team fired femtosecond laser pulses at a sample of magnesium atoms, which could absorb multiple infrared photons from the laser to form Mg2. This process is rare, but the researchers found they could alter the Mg2 yield by changing the pulse shape. In particular, a positive chirp (i.e., a pulse whose frequency steadily increases with time) boosted the yield by a factor of 5 over an unshaped pulse. To explain this chirp dependence, the team constructed a model that showed the pulse shape affects transitions between vibrational levels in an intermediate state. With this understanding, they optimized the pulse shape using a feedback system, gaining a further 35% in the reaction yield.

This research is published in Physical Review Letters.

–Michael Schirber


Subject Areas

OpticsChemical Physics

Related Articles

Quantum Circuit Tackles “Diabolical” Photochemical Process
Chemical Physics

Quantum Circuit Tackles “Diabolical” Photochemical Process

A quantum device shows promise for simulating molecular dynamics in a difficult-to-model photochemical process that is relevant to vision. Read More »

Twinkling of a Shrinking Droplet Reveals Hidden Complexity
Atomic and Molecular Physics

Twinkling of a Shrinking Droplet Reveals Hidden Complexity

Captivating patterns found in the light scattered by an evaporating water droplet could be used to infer the properties of the droplet as it shrinks. Read More »

Air Waveguide from “Donut” Laser Beams
Plasmonics

Air Waveguide from “Donut” Laser Beams

A waveguide sculpted in air with lasers transmits light over a distance of nearly 50 meters, which is 60 times farther than previous air-waveguide schemes. Read More »

More Articles