# Synopsis: Chemistry of an Interface

Experiments pinpoint the effects of lanthanum composition on the conducting properties of the ${\text{LaAlO}}_{3}-{\text{SrTiO}}_{3}$ interface.

It sounds implausible, but two poor electrical conductors can be the building blocks for an excellent one. In 2004, experimentalists observed that thin films of ${\text{LaAlO}}_{3}$ and ${\text{SrTiO}}_{3}$, both wide-band-gap insulators, formed a metal at their interface. Later experiments showed this two-dimensional metal could support unusual transport properties, including superconductivity. Explanations for these and other properties of the interface often invoke (among other things) oxygen vacancies, but a new systematic study cautions that even in the absence of such oxygen defects, small changes in the amount of lanthanum ($\text{La}$) in the ${\text{LaAlO}}_{3}$ layer can have large effects on the interfacial electrical resistance. As reported in Physical Review Letters, whether there is an excess or deficiency of La depends on how the samples are fabricated, but the difference can be easily missed by conventional sample characterization.

Eric Breckenfeld and colleagues at the University of Illinois, Urbana-Champaign followed a standard recipe for preparing their ${\text{LaAlO}}_{3}$-${\text{SrTiO}}_{3}$ heterostructures: they used a laser to ablate $\text{La}$ and $\text{Al}$ from a ${\text{LaAlO}}_{3}$ target and deposited the atoms onto a ${\text{SrTiO}}_{3}$ substrate, controlling for oxygen content with a variable oxygen partial pressure. Careful elemental analysis of the samples with x rays revealed the ratio of $\text{La}$ to $\text{Al}$ depended on the laser energy density: The deviations were small enough to be missed by characterization probes like electron diffraction and atomic force microscopy, but even a few percent La deficiency led to a one-million-fold drop in the resistance of the interface. Changing the partial pressure of oxygen, however, had a much smaller effect. Based on the authors’ findings, future work aimed at understanding the physics of this interesting interface will have to take into account the role of the chemistry of the materials. – Jessica Thomas

More Features »

### Announcements

More Announcements »

Nanophysics

Fluid Dynamics

## Related Articles

Graphene

### Synopsis: Crumpled Graphene

The crumpling of graphene sheets explains a “soft spot” in the material’s mechanical response. Read More »

Materials Science

### Synopsis: Powering up Magnetization

New theoretical work identifies a dynamic form of multiferroic behavior, in which a time-varying electric polarization induces magnetization in a material. Read More »

Materials Science

### Viewpoint: How to Make Devices with Weyl Materials

Weyl semimetals could be used to build a range of electronic devices, from superlenses for scanning tunneling microscopes to transistors. Read More »